The footage shows Saif al-Islam wearing traditional robes with a scarf pulled over his head sitting on board a plane bound for Zintan.
In this video, a bearded, bespectacled Saif al-Islam Gaddafi is seen sitting anxiously only speaking briefly in Arabic.
When asked by a Reuters reporter on the flight to Zintan if he was feeling all right, Saif al-Islam simply replied, "Yes." He told her he had been injured in a NATO air strike a month ago.
The NTC's Justice Minister Mohammed al-Allagui said he would be transferred to Tripoli.
Saif al-Islam Gaddafi and his four, armed male companions had been captured without a fight after a month-long search.